Acetyl chloride is a clear, corrosive and fuming liquid. It is prepared by reacting acetic acid with a halogenating agent such as phosphorusiii. Ac151270000, ac151270010, ac151270025, ac151275000, ac219470000, ac219470250, ac219472500, a27250 synonyms. Chloroacetyl chloride reacts vigorously with water to generate gaseous hcl. Acetyl acetone peroxide with more than 9 percent by mass active oxygen forbidden acetyl benzoyl peroxide, solid, or with more than 40. View or download the acetyl chloride msds material safety data sheet or sds for 822252 from merck. Identification of the substancemixture and of the companyundertaking. Dichloroacetyl chloride is a reactive chemical and a dangerous explosion hazard. Chlorophacinone is a diarylmethane and a betatriketone. First aid measures general advice consult a physician. Acetyl acetone cas no 123546 material safety data sheet sds msds. If released to the atmosphere, acetyl acetone is expected to exist in the vapor phase. However, the samples can not be stored for more than 10 days without significant degradation, even with freezing.
Provide an emergency eye wash fountain and quick drench shower in. Identification dichloroacetyl chloride is a fuming liquid with a sharp, penetrating odor. Methylene chloride revision date 28nov2019 eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Acetyl chloride reacts vigorously with water to generate gaseous hcl. C2h2cl2o, clch2cocl, acetyl chloride, chloro, chloroacetic acid chloride, chloroacetic chloride.
Precautionary statements p210 keep away from heat, hot. Msds contains all of the information required by those regulations. Lysozyme from chicken egg white l6876 sigmaaldrich. Acetyl chloride, reagent grade, 98% ch3cocl sigmaaldrich. Acetyl chloride undergoes reaction with decalin and aluminum trichloride to afford a tricyclic enol ether. First aid measures remove victim to fresh air and keep at rest in a position comfortable for breathing. Safety data sheet according to 29cfr19101200 and ghs rev. Commercially available as oil concentrate and as dust concentrate. Ib2, t8, tp2 154 202 acetyl chloride 3, 8 un1717 ii flammable liquid, corrosive a3, a7, ib1, n34, t8, tp2 150 202 acetyl cyclohexanesulfonyl peroxide, with more than. Find msds or sds, a coa, data sheets and more information. Ou chemical safety data no longer updated more details. Chloroacetyl chloride can be used for chloroacetylation and chemical modification of poly glycidyl methacrylate. Show this safety data sheet to the doctor in attendance. Sigmaaldrich offers a number of acetyl chloride products.
Articles of chloroacetyl chloride are included as well. P261 avoid breathing dust fume gas mist vapours spray. It is employed as a linker to prepare dendrimers and also used in the synthesis of various conjugated aromatic small molecules. Chemtrec 8004249300 outside usa 7035273887 1216 6th ave n kent wa 98032 phone. Chloroacetyl chloride is on the hazardous substance. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. It is used as a tear gas and to make other chemicals. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Identification product name acetyl chloride cat no.
Material safety data sheet date last revised 02182009 by m. Cellulose samples extracted from cornhusk have been successfully acetylated in an ionic liquid 1allyl3methylimidazolium chloride amimcl. Based on a scenario where the chemical is spilled into an excess of water at least 5 fold excess of water, half of the maximum theoretical yield of hydrogen chloride gas will be created in 1. However, we make no warranty of merchantability or any other warranty, express or. Based on a scenario where the chemical is spilled into an excess of water at least 5 fold excess of water, half of the maximum theoretical yield of hydrogen chloride gas will be created in 0. Acetyl chloride material safety data sheet cas no 75365. Acetonesoluble cellulose acetates prepared by onestep. Safety data sheet northwest missouri state university. Our msds database is an easy to use, do it yourself tool, and best of all. It has been reported that acetyl chloride can be used as a fluorescence histochemical in combination with formaldehyde to identify tryptophylpeptidecontaining endocrine cells of the hypophysis.
It undergoes violently hydrolysis in presence of atmospheric moisture. Safety data sheet creation date 07sep2010 revision date 25apr2019 revision number 6 1. Chloroacetyl chloride was used to study the in vitro metabolism of chloroacetamide. This material does not contain any class 1 ozone depletors. Wear splash resistant safety goggles with a faceshield. A27250 casno 75365 synonyms ethanoyl chloride certified recommended use laboratory chemicals. Acetyl chloridemethanol as a convenient reagent for. Buy 2,6dimethylphenoxyacetylchloride cas 20143480, a biochemical for proteomics research, from santa cruz. Acetyl acetone material safety data sheet cas no 123546. Incompatible with strong bases, alcohols,strong oxidizing agents. Affinisol hpmcas for spraydried dispersion sdd solving.
It promotes the cyclopropanation of alkene with dibromomethane or diiodomethane in the presence of zn dust and copper chloride in ether. Material description company issue dateflannery, incorporated november 2007. Phenylacetyl chloride is used as a key precursor in the total synthesis of vialinin b. Acetyl chloride is an acid chloride reagent used for acetylation in organic synthesis reactions such as esterification and the friedelcrafts reaction. Chloroacetyl chloride, chloroacetyl chloride 98%, supply chloroacetyl chloride,best quality chloroacetyl chloride.
It is recognized that ketene and acetyl chloride will also react. Any selfcontained breathing apparatus that has a full facepiece and is operated in a pressuredemand or other positivepressure mode. Acetyl chloride cas no 75365 material safety data sheet sds msds. You can obtain copies of sampling results from your employer. Store in a cool, dry wellventilated location, away from any area where the fire hazard may be acute. Affinisol hpmcas for spraydried dispersion sdd hpmcas to the solution to give a clear to slightly opaque final solution with 25 wt% api to 75 wt% affinisol hpmcas ratio. Vaporphase acetyl acetone is expected to degrade by reaction with photochemically produced hydroxyl radicals estimated halflife of 14 days. Canadian ingredient disclosure list section 16 additional information msds creation date. Sds of acetyl chloride, safety data sheets, cas 75365.
Section 1 chemical product and company identification product name chloroacetyl chloride statement of hazardous nature considered a hazardous substance according to osha 29 cfr 1910. Uses advised against food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet. Reason for citation dichloroacetyl chloride is on the hazardous substance list because it is cited by dot and nfpa. Chemical sampling information database on chloroacetyl chloride. Chloroacetyl chloride causes the acylation of cyanopyrazoline during the synthesis of secondary aminesubstituted cyanopyrazoline derivatives.
Handling and storage protect against physical damage. Monoclonal antibody trial size samples click here for a free sample home. Fedex ground hazardous materials table please refer to the. A quantitative formation of amine hydrochlorides, b carboxylate ester formation, c mild removal of nbocprotective group. This chemical is considered hazardous by the 2012 osha hazard. Chloro acetyl chloride cas no 79049 material safety data sheet sds msds. This material does not contain any hazardous air pollutants.